Characteristics and EOR mechanisms of nanofluids permeation flooding for tight oil

Abstract

Tight oil reservoir development is faced with the key technical problem that “water cannot be injected and oil cannot be produced” yet. With the diphenyl ethers water-soluble (gemini) surfactants as water phase shell and C 10 –C 14 straight-chain hydrocarbon compounds as oil phase kernel, a nanofluids permeation flooding system was prepared by microemulsion technology, and its characteristics and EOR mechanisms were evaluated through experiments. The system has the following five characteristics: (1) “Small-size liquid”: the average particle size of the system is less than 30 nm, which can greatly reduce the starting pressure gradient of water injection, and effectively enter and expand the sweep volume of micro-nano matrix; (2) “Small-size oil” : the system can break the crude oil into “small-size oil” under the flow condition, which can greatly improve the percolation ability and displacement efficiency of the crude oil in the micro-nano matrix; (3) Dual-phase wetting: the system has contact angles with the water-wet and oil-wet interfaces of (46±1)° and (68±1)° respectively, and makes it possible for capillarity to work fully under complex wetting conditions of the reservoir; (4) High surface activity: the interfacial tension between the system and crude oil from a tight oil reservoir in Xinjiang is 10 −3 –10 −2 mN/m, indicating the system can effectively improve the displacement efficiency of oil in fine pore throats; (5) Demulsification and viscosity reduction: the system has a demulsification and viscosity reduction rate of more than 80% to inversely emulsified crude oil from a tight oil reservoir in Xinjiang, so it can improve the mobility of crude oil in the reservoir and wellbore. The system can be used to increase oil production by fracturing in tight reservoirs, replenish formation energy by reducing injection pressure and increasing injection rate, and enhance oil recovery by displacement and cyclic injection, providing key technical support for effective production and efficient development and recovery enhancement of tight reservoirs.