Abstract
A novel thermokinetic research method for determination of rate constants of simple-order reaction in batch conduction calorimeter under isothermal condition, the characteristic parameter method, is proposed in this paper. Only needing the characteristic time parameter tm obtained from the measured thermoanalytical curve, the kinetic parameters of reactions studied can be calculated conveniently with this method. The saponifications of ethyl propionate and ethyl acetate in aqueous ethanol solvent, the polymerization of acrylamide in aqueous solution, the ring opening reaction of epichlorohydrin with hydrobromic acid have been studied. The experimental results indicate that the characteristic parameter method for simple-order reaction is correct.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.