Characteristic and mechanism analysis of sludge polymer by adding carboxymethyl cellulose-g-acrylic acid for sludge utilization.

Abstract

Herein, a nutrient water retention agent is prepared by fully mixing sludge with carboxymethyl cellulose-g-acrylic acid (CMC-g-AA) gel and nanoscale zero-valent iron (nZVI) using polymer modifying curing technology. Experimental results show that when CMC:AA = 1:12 and CMC-g-AA gel content is 50%, sludge polymer has better water absorption and retention performance and the water retention time is extended for ∼14 days. At the same time, sludge polymer can preserve the characteristics of nutrient-rich elements and organic matter and promote plant growth. The addition of nZVI has a significant impact on reducing the risk of heavy metal toxic leaching in sludge. Moreover, analysis of variance and multiple comparisons shows that sludge polymer's particle size and water absorption times have significant effects on the water absorption and retention properties of sludge polymer. Scanning electron microscopy, X-ray diffraction, Fourier-transform infrared spectroscopy and 13C-nuclear magnetic resonance analyses show that the addition of an appropriate amount of gel could increase the number of hydrophilic groups and hydrophilic mineral components in sludge polymer, increase its overall porosity and improve its water absorption and retention properties.