Abstract
First in this chapter, we will focus on explaining the essential information required to study the relatively new area in the field of chemistry called statistical thermodynamic. Such information includes theoretical and conceptual frameworks of total energy, accessible energy levels and energy states, indistinguishable and distinguishable particles, permitted number of particles per energy state, and also if the particles are dependent or independent. Then, we will identify the term of macrostate and explore the taken procedures to find the distribution of identical distinguishable and indistinguishable particles with or without a limit on the number of particles per energy state. Finally, we develop an understanding of the microstate, and the most probable macrostate.
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