Abstract
The hydrosilylation reaction refers to the addition reaction of silicon hydride species to unsaturated bonds such as carbon–carbon double bonds, carbon–oxygen double bonds, and carbon–nitrogen double bonds. The past few decades witness the remarkable progress in this field, and hydrosilylation has been developed to be one of the most important industrial applications. This chapter will discuss recent representative asymmetric hydrosilylation reactions catalyzed by copper complex with chiral phosphine ligand. This chapter also provides a brief summary on the progress in this field catalyzed by copper with chiral phosphine ligand.
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