Abstract

Electrochemical energy systems are significantly considered as clean energy resources and promising technologies to meet modern society's future desire for sustainability. For the practical implementation of such electrochemical technologies, well-designed and highly competent electrocatalysts are in high demand nowadays. Metal-organic frameworks (MOFs)-based advanced electrocatalysts, which have adjustable structure, inherent characteristics, and stability, have recently been regarded as one of the most efficient electrocatalysts for energy storage and conversion processes, including hydrogen evolution reaction (HER), oxygen evolution reaction (OER), oxygen reduction reaction (ORR), carbon dioxide reduction reaction (CO2RR), and nitrogen reduction reaction (NRR). This chapter provides a comprehensive review of structural design and synthesis strategies, as well as recent developments in MOF-based nanomaterials for diverse electrochemical energy conversion applications. These efforts will pave the way for MOF-based electrocatalysts to be developed for more efficient and long-lasting electrochemical energy conversion and storage technologies.

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