Chapter 3 - Characterization of natural organic matter

Abstract

Worldwide reports over the last few decades have shown that the amount of natural organic matter (NOM) in surface water is continuously increasing, which has an adverse effect on drinking water purification. For many practical and hygienic reasons, the presence of NOM in drinking water is undesirable. Various technologies have been proposed for NOM removal with varying degrees of success. The properties and amount of NOM, however, can significantly affect the process efficiency. To improve and optimize these processes, it is essential to characterize and quantify NOM at various points during purification and treatment. It is also important to be able to understand and predict the reactivity of NOM or its fractions at different stages of the process. Methods used in the characterization of NOM include resin adsorption, size exclusion chromatography (SEC), nuclear magnetic resonance (NMR) spectroscopy, and fluorescence spectroscopy. The NOM in water has been quantified with parameters including ultraviolet and visible, total organic carbon, and specific UV-absorbance. More comprehensive analytical methods for determining NOM structures have been developed recently: liquid chromatography-mass spectrometry (LC-MS), pyrolysis gas chromatography-mass spectrometry (Py-GC-MS), multidimensional NMR techniques, and Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS). This chapter focuses on the methods used for the characterization and quantification of NOM in relation to drinking water treatment.