Abstract

Abstract In the coordination sphere of substituted cyclopentadienyl transition-metal complex fragments PO, cyclo-P33−, open-edged P6 benzvalene and As6 Dewar benzene, cyclo-As8 as well as open-edged E10 dihydrofulvalenes (E = P, As) have been stabilized for the first time. Source for the Pn− and Asn − units are white phosphorus, P4, and yellow arsenic, As4, respectively.

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