Abstract

Deep-fat frying is an important process used worldwide for the preparation of foods. Due to oxidation, hydrolysis, decomposition and oligomerization, numerous polar compounds are formed. These compounds change the physical, nutritional and sensory properties of the oil or fat. The standard methods of the German Society for Fat Science for the assessment of the quality of frying fats are time consuming and cost intensive. Therefore, alternative cost-effective and sensitive rapid methods, which ideally allow the quantitative determination of the quality of frying fats “in-line” in the deep-frying pan are needed. Sunflower oil and palm fat were thermally and oxidatively degraded in a beaker at atmospheric pressure under intensive stirring for 76 h at 175 °C. To evaluate the development of the physical properties during heat treatment, the viscosity and dielectric constant of these oils were measured. The temperature in a deep-frying pan can vary within a wide range (160–190 °C), and the viscosity and dielectric constant show a strong temperature dependence. Therefore, it was necessary to measure the temperature dependence of the viscosity and dielectric constant of the different degraded oils. Additionally, their chemical properties were characterized by high-performance gel permeation chromatography and Fourier-transform infrared spectroscopy (FTIR). The determination of the dielectric constant, which is directly correlated with the concentration of polar compounds, seems to be the best method for the assessment of the quality of used frying oils.

Highlights

  • IntroductionDeep-fat frying is an important process used worldwide for the preparation of foods [1,2]

  • Deep-fat frying is an important process used worldwide for the preparation of foods [1,2].Under the conditions of high temperature (160–190 ◦ C), air and moisture, a great number of chemical reactions occur in the oil

  • These rapid tests should exhibit the following characteristics: (1) correlation with internationally recognized standard methods, (2) able to provide an objective index, (3) easy to use, (4) safe for use in a food processing/preparation area, (5) able to quantify oil degradation, (6) field rugged. Such rapid test methods include the measurement of the dielectric constant [13,14], which increases with increasing levels of polar material in the used frying oil, and the measurement of viscosity, which increases with increasing levels of polymers [15,16]

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Summary

Introduction

Deep-fat frying is an important process used worldwide for the preparation of foods [1,2]. The search for rapid test methods to determine the quality of frying oils during the processing is an ongoing challenge, and the 3rd International Symposium on Deep-Fat Frying recommended the use of rapid tests for monitoring oil quality [12] These rapid tests should exhibit the following characteristics: (1) correlation with internationally recognized standard methods, (2) able to provide an objective index, (3) easy to use, (4) safe for use in a food processing/preparation area,. (5) able to quantify oil degradation, (6) field rugged Such rapid test methods include the measurement of the dielectric constant [13,14], which increases with increasing levels of polar material in the used frying oil, and the measurement of viscosity, which increases with increasing levels of polymers [15,16]. The heat-treated vegetable oils were characterized by high-performance gel permeation chromatography and FTIR-ATR spectroscopy

Thermal and Oxidative Degradation of Oil Samples
Viscosity
Dielectric Constant
Dielectric
Fourier-Transform
Conclusions
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