Changes in phenolic composition and antioxidant activity of white wine during bottle storage: Accelerated browning test versus bottle storage

Abstract

Polyphenol content, antioxidant activity, reducing power, colour and changes during storage over nine months in bottles and after accelerated browning were studied in selected Hellenic varietal white wines. The following phenolic compounds were identified in the wines: Caftaric, coutaric, fertaric, ferulic, caffeic, p-coumaric and gallic acids, (+)-catechin and (−)-epicatechin. The results showed that the contents of most of the phenols diminished with time, with the exception of caffeic, ferulic and p-coumaric acids. Antioxidant activity increased with storage whereas reducing power remained significantly unaffected. Accelerated browning did not significantly alter the concentrations of tartaric acid esters but it increased the concentrations of the hydroxycinnamic and gallic acids. (+)-Catechin concentration was not affected while (−)-epicatechin decreased. Antioxidant activity did not show any significant change but reducing power was reduced after the end of the browning test. As for the absorbance at 420 nm, it remained unchanged during storage, but it was significantly increased after accelerated browning.