Abstract
The molecular KLL Auger spectra of fluorine have been measured from HF, LiF, Naf and KF. The change in the ionic character of the chemical bond is clearly seen as narrowing of the KL 2,3L 2,3 structure on going from HF to KF. Theoretical calculations using the multiconfigurational CASSCF method are also found to predict well these changes. Comparison with the calculated KLL Auger spectrum of the fluorine ion F − verifies the conclusions.
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