Abstract
Herein, we report the kinetics of pseudo[1]rotaxane formation from permethyl α-cyclodextrin attached to a flexible-chain-substituted diphenylethynylene. When the chain is an alkyl group, the rate of formation shows different trends over three regions of chain length: deceleration (chain length = 1–3), acceleration (4–8), and re-deceleration (>12). This behavior is driven by a relative decrease in the ΔH‡ of the transition.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
