Abstract
The interrelationship between the structure, phase composition, and transport characteristics of solid electrolytes based on ZrO2 has been studied as dependent on the content of stabilizing Y2O3 additive. It is established that twin boundaries do not lead to the appearance of additional mechanism of ionic conductivity acceleration in ZrO2–Y2O3 crystals. The maximum conductivity has been observed in ZrO2–(8–10) mol % Y2O3 crystals containing a t” phase, in which oxygen atoms are displaced from high-symmetry positions characteristic of the cubic phase.
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