Abstract

The favorable downscaling behavior of photoacoustic spectroscopy has provoked in recent years a growing interest in the miniaturization of photoacoustic sensors. The individual components of the sensor, namely widely tunable quantum cascade lasers, low loss mid infrared (mid-IR) waveguides, and efficient microelectromechanical systems (MEMS) microphones are becoming available in complementary metal–oxide–semiconductor (CMOS) compatible technologies. This paves the way for the joint processes of miniaturization and full integration. Recently, a prototype microsensor has been designed by the means of a specifically designed coupled optical-acoustic model. This paper discusses the new, or more intense, challenges faced if downscaling is continued. The first limitation in miniaturization is physical: the light source modulation, which matches the increasing cell acoustic resonance frequency, must be kept much slower than the collisional relaxation process. Secondly, from the acoustic modeling point of view, one faces the limit of validity of the continuum hypothesis. Namely, at some point, velocity slip and temperature jump boundary conditions must be used, instead of the continuous boundary conditions, which are valid at the macro-scale. Finally, on the technological side, solutions exist to realize a complete lab-on-a-chip, even if it remains a demanding integration problem.

Highlights

  • Photoacoustic (PA) spectroscopy is a well-established technique and numerous gas sensors designs, relying on a single cavity, based on Helmholtz resonance, or enhanced by quartz tuning forks have been imagined and implemented [1]

  • In a previous article [14], a coupled optics-acoustics model dedicated to the simulation of miniaturized and integrated PA gas detectors has been presented

  • The optical model generally used for PA sensors assimilates the laser illumination geometry to a straight beam for which the flux follows a Gaussian distribution within a cross section [16,17]

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Summary

Introduction

Photoacoustic (PA) spectroscopy is a well-established technique and numerous gas sensors designs, relying on a single cavity, based on Helmholtz resonance, or enhanced by quartz tuning forks have been imagined and implemented [1]. Other notable progress in the size reduction direction has been performed by Gorelik et al [5], with inclined geometry cells (~500 mm internal volume), who reached, for instance, a detection limit of ~10 ppm for ammonia On their side, Karioja et al [6] implemented a low-temperature co-fired ceramics technology to build a. In a previous article [14], a coupled optics-acoustics model dedicated to the simulation of miniaturized and integrated PA gas detectors has been presented Using this model and taking into account the design rules of MEMS technologies, a miniaturized DHR cell has been devised (Figure 1). This μ-PA sensor is composed of three different wafers, assembled by eutectic bonding. Even though the focus is placed here on the μ-PA cell currently under fabrication, our expectation is to provide as general insights as possible

Challenges in Modeling and Simulation
Downscaling of the Optical Model
Molecular Relaxation
Downscaling of the Acoustic Model
Validity of the Continuum Model
Technological Challenges
Findings
Conclusions
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