Abstract
AbstractAsymmetric Olefin Metathesis (AOM) represents a highly versatile synthetic tool to lead to relevant chiral building blocks with excellent enantiopurity. As the Z‐alkene moiety is ubiquitous in a wide range of natural products, the development of catalysts which are able to control both the Z‐selectivity and the enantioselectivity of metathesis transformations is in high demands. This review aims to provide a comprehensive overview covering all the breakthroughs accomplished in the field of challenging Z‐enantioselective olefin metathesis, which is of interest in the total synthesis of complex molecules.
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