Abstract

One approach to obtaining electro-optic or magneto-optic modulation in an integrated optic structure is to use a transparent film on an “active” (electro- or magneto-optic) optical substrate. Since the most useful active optical materials have relatively high refractive indices which preclude the use of oxide glasses as the transparent thin film, we have investigated the possibility of using higher index chalcogenide glasses in this configuration. Preliminary waveguiding studies were performed on a model system consisting of an As2S3 film on a LiNbO3 substrate which demonstrated the feasibility of using chalcogenide glasses in this regard. The optical and mechanical properties of a suitable glass system, As-Ge-S, were then characterized. The characterization consisted of developing empirical formulas based on the type of bonding present in the glass which can be used to predict the relevant properties of a glass as a function of its composition. These formulas allow selection of optimum glass compositions to match a variety of electro-optic and magneto-optic substrates.

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