Abstract
To each his own: Copolymerization of styrene and isoprene by catalysts Sc1 (syndiospecific for styrene) and Sc2 (cis-1,4-specific for isoprene) with a chain-shuttling agent iBu3Al gives block copolymers of syndiotactic polystyrene (sPS) and cis-1,4-polyisoprene (PIP). Replacement of Sc2 with Sc3 (high 3,4-selectivity for isoprene polymerization) gives selectively copolymers having sPS and 3,4-PIP blocks. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
