Abstract

The title compound, 2C4H8N3O+·SO4 2−, crystallizes with two creatininium cations and one sulfate anion in the asymmetric unit. Cations and anions dimerize through N—H...O hydrogen bonds forming R 2 2(8) ring motifs. Furthermore, these rings are connected via N—H...O hydrogen bonds, leading to C 2 2(6) and C 2 2(8) chain motifs. These interactions lead to a parallel set of hydrogen-bonded lamellar aggregations propagating along the c axis of the unit cell. Another cation is situated above these sheets, leading to a grid-like structure.

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