Abstract
Accurate CH + ab initio potential energy curves were calculated. The quality of the potentials was checked by comparing experimental and calculated CH + absorption cross-sections for various rotational transitions. The relative importance of couplings and corrections to the Born–Oppenheimer approximation was studied. When relativistic corrections were included and core electrons also correlated, good agreement was achieved between the experiment and the theory for the photodissociation cross-section. The new potentials were used to calculate the radiative association cross-section.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
