CFD simulation of a transpiring‐wall SCWO reactor: Formation and optimization of the water film

Abstract

A two‐dimensional axisymmetric computational fluid dynamics model of a transpiring wall reactor for supercritical water oxidation was developed using the commercial software Fluent 6.3. Numerical model was validated by comparisons with experimental temperature profiles and product properties (total organic carbon and CO). Compared with the transpiration intensity, the transpiring water temperature was found to have a more significant influence on the reaction zone. An assumption that an ideal corrosion and salt deposition inhibitive water film can be formed when the temperature of the inner surface of the porous tube is less than 374°C was made. It was observed that lowering transpiring water temperature is conducive to the formation of the water film at the expense of feed degradation. The appropriate mass flux ratio between the total transpiring flow and the core flow was determined at 0.05 based on the formation of the water film and feed degradation. © 2015 American Institute of Chemical Engineers AIChE J, 62: 195–206, 2016