CFD simulation for CO2 separation using diamond-structured thermally rearranged (TR) polymer membrane: Effect of CO2 feed concentration, feed pressure and temperature

Abstract

Abstract CO2 separation in natural gas purification is important in improving the properties of natural gas such as energy content, volume and corrosivity. Membrane separation using TR-450 polymer membrane is a potential approach to remove CO2 from natural gas efficiently. The study of CO2/CH4 binary gas mixture separation was simulated using a thermally-rearranged (TR) HAB- 6FDA membrane at 450 °C with a partial part of Schwarz Diamond structure because it exhibits advanced mechanical properties with low stiffness for relatively high strength. TR-450 membrane exhibits excellent separation performance that has the potential to exceed the Robeson plot 1991. Computational fluid dynamics (CFD) was used to simulate the fluid behavior within the geometry created using CAD software. The effect of feed pressure, temperature and CO2 feed concentration on the separation performance of TR-450 membrane was also studied. The results indicated that an increase in feed pressure leads to a decrease in CO2 recovery, hence the lower separation performance. It was also found that increasing the feed temperature leads to an increase in CO2 recovery. Concerning the concentration of CO2 in the feed, elevated levels impact the performance of membrane separation. The enhanced membrane separation performance demonstrated by the TR-450 membrane under various conditions underscores the necessity for additional investigation to unveil its potential in industrial gas separation applications.