Cesium sorption on studtite (UO2O2·4H2O)

Abstract

AbstractOne of the mechanisms that may decrease the mobility of cesium released from spent fuel in a high level nuclear waste repository (HLNW) is its sorption onto uranyl-containing alteration phases formed on the spent fuel surface such as studtite (UO2O2·4H2O). The results obtained in this work show that sorption is a very fast process; cesium in solution is sorbed in less than one hour at pH 5. Sorption as a function of initial concentration in solution was also studied between initial cesium concentrations ranging from 7.6×10−9 mol dm−3to 1.0×10−3 mol dm−3. The data have been modelled considering a Freundlich isotherm, withKFandnvalues of 10±1, and 1.4±0.1, respectively (r2=0.998). Sorption is very dependent on ionic strength, suggesting that cesium sorbs onto studtite by forming an outer-sphere complex involving electrostatic interactions. Sorption is observed to be very low at acidic pH, while relatively high at alkaline pH (i.e., almost 60% of the total cesium concentration in solution is sorbed at pH>9). The results point to the importance of sorption processes on uranyl alteration phases on the retention of radionuclides.