Abstract

The centrifugal distortion effects for a molecule containing two symmetric internal rotors are formulated. The explicit expressions that relate the distortion constants to fundamental molecular parameters are given, which are applicable for analysing molecular structure from the parameters determined from a fit-to-observed spectrum or for calculating the centrifugal distortion constants from well known fundamental molecular parameters. The reduced torsion - rotation Hamiltonian is given for a molecule with two internal rotors with a symmetry plane which contains both internal rotation axes.

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