Abstract
A novel micro-solid phase extraction protocol based on a new molecularly imprinted polymer (MIP) sorbent is reported for the isolation of chlorpyrifos from rice, juice and fish samples followed by spectrophotometric determination. The MIP sorbent was packed into a pipette tip. The type and volume of the eluent, pH, mass of MIP, sample volume, and number of extraction and elution cycles were evaluated utilizing a one-variable-at-a-time protocol, central composite design, and Box-Behnken design. The results demonstrated the optimum performance of central composite design. The linear range under the optimal conditions for chlorpyrifos was from 1 to 1000 µg L−1 with a limit of detection of 0.17 µg L−1 and a relative standard deviation less than 4.3%. The protocol was successfully employed for the determination of trace concentrations of chlorpyrifos in fish, juice, and rice.
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