Abstract
Layered double hydroxides (LDHs) has been regarded as one of the most potential photocatalysts for degradation of the pollutants, due to the tunable elements in the laminates, high surface area and exposed active sites. Developing a photocatalyst with a visible light activity and fast charge separation efficiency is a main research focus. In this work, a central-collapsed CoFeAl-LDHs was formed via the selective etching Al3+ in the laminates, which relied on the function of OH– produced by urea hydrolysis. The Central-collapsed structure of CoFeAl-LDHs exhibited enhanced adsorption activity and photocatalytic efficiency. The results show that the pseudo-second-order kinetic model and the Langmuir model are suitable for adsorption behavior. This etching cavity is beneficial to the adsorption of MB and provides a better platform for the direct interaction between MB and CoFeAl-LDHs. The morphology and photoelectrochemical properties of the central-collapsed structure of LDHs were characterized and used to explore the relationship between the etching degree and photocatalytic activity. The photocatalytic properties of all the samples under visible light irradiation were evaluated, and LDH-6 has the best photocatalytic activity. This work provides a novel approach for the fabrication of central-collapsed structure of layered double hydroxides photocatalysts to meet environmental and energy requirements.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
