Abstract
The priority-chronological aspect of research and technological development in the field of SiC-containing HCBS and ceramic castables in the systems Al2O3‒SiO2‒SiC and Al2O3‒SiO2‒SiC‒C is characterized. The results of studies on the effect of the firing temperature and prolonged (up to 100 h) high-temperature heat treatment on the oxidation kinetics of SiC of different dispersion and content are considered. A noticeable oxidation, accompanied by an increase in the mass and growth of samples, is noted after 1200 °C and significant at 1300‒1400 °C. The effect of the firing temperature in the range of 1000‒1400 °C and long holding in a tunnel furnace (60 h at 1300‒1400 °C) on the dynamics of phase transformations and the structure of samples of the matrix system based on HCBS of composite composition (bauxite + 11 % VFQG), as well as with an additional content of 15% SiC. In contrast to firing in air, during the service of monolithic gutter masses in the Al2O3‒SiO2‒SiC‒C system, the working surface of concrete is largely isolated from the air due to cast iron and slag. This drastically reduces the rate of both SiC oxidation and carbon burnout. The zonal structure of the lining is characterized. The data on the effect of heating and cooling on the modulus of elasticity of ceramic castable are presented.
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