Cement-based materials: Pozzolanic activities of mineral additions are compromised by the presence of reactive oxides

Abstract

Presence of reactive oxides, such as sodium, potassium, and magnesium oxides, compromise the pozzolanic activities of mineral additions to cement-based materials. That is because these oxides react with water to form hydroxides. Subsequently, these hydroxides may react with the otherwise non-reactive oxides, such as silicon and aluminum oxides, to form various silicate and aluminate phases in the cement-based material, that finally compete with the desired CSH phase. Further, the strong pozzolanic activity of the silica fume is seemingly due to its large ability to form the calcium silicate hydrated systems when compared with both metakaolin and fly ashes. All these results have been established by X-ray fluorescence, microstructural, and chemometric analyses that were applied to investigate the pozzolanic activities, thermodynamic, structural, and mechanical properties of a set of mineral systems widely applied to cement-based materials (silica fume, metakaolin, and fly ashes). The chemometric analyses revealed that the materials prepared with silica fume exhibited the largest mechanical properties, whereas the reference the lowest. The cement-based materials with metakaolin and fly ashes present intermediary resistances and similar behaviors. In conclusion, strict control of the purity of the material always needs to be performed to obtain mineral systems with powerful pozzolanic activities.