Abstract
A multi-functional hybrid of cellulose acetate with cadmium sulfide and Methylene blue (CA/CdS/MB) in a bead composition was synthesized and investigated as a photosensor-adsorbent for the rapid, selective, and sensitive detection, and adsorption of Cu(II) ions. These hybrid CA-modified beads are composed of multiple adsorption active sites and possess a surface area of 58 cm2g-1. They are an efficient adsorbent with a maximum adsorption capacity of 0.57mgg-1. Photoelectrochemical (PEC) detection of Cu(II) was accomplished by modifying the beads on a glassy carbon electrode. The beads containing 20mmol of sulfur displayed the widest linear analyticalrange (0.1-290nM) and the lowest detection limit (16.9nM) for Cu(II) with high selectivity and reliable reproducibility. The successful application of the beads has provided a new insight for the selection of a responsive photoactive material for a PEC assay, as well as an effective adsorbent material for Cu(II) ions. Graphical abstract A multi-functional hybrid of cellulose acetate with cadmium sulfide and Methylene blue (CA/CdS/MB) in a bead composition was synthesized and investigated as a photosensor-adsorbent for the rapid, selective and sensitive detection and adsorption of Cu(II) ions.
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