Cellular Structure of EVA/ATH Halogen-free Flame-retardant Foams

Abstract

Composites of etylene vinyl acetate (EVA)/aluminum trihydroxide (ATH) (up to 70 wt%) were foamed to create new materials with good fire retardancy properties and low weight, proving the feasibility of developing cellular structures when high levels of halogen-free flame retardants (HFFR) are included. An experimental study was carried out to explore the effects of chemical composition on cellular structure as well as the effect of structure on thermal stability, mechanical and combustion properties. Sample fabrication was carried out using an improved compression molding route consisting of polymer compounding, precursor preparation and foaming under pressure. The polymer matrix consisted of EVA as well as certain amount of linear low-density polyethylene-maleic anhydride as coupling agent. The inorganic filler used was ATH ranging from 0 wt% to 70 wt%. Furthermore, azodicarbonamide was used as chemical blowing agent. Foamed samples with cell sizes below 100 µm were produced. These samples showed similar fire retardancy than their solid precursors. The compatibilization was proved indispensable to achieve a good adhesion between mineral filler and polymer and to improve the cellular structure. The increase of the amount of filler has an interesting effect on the cellular structure, going from a closed-cell (up to 50 wt% of ATH) to an open-cell cellular structure (60 wt% of ATH or more). The feasibility of producing HFFR cellular materials has been demonstrated as a result of this investigation, leading to a notable reduction of material compared to the solid one and to new properties which can result in new applications.