Cellular plagioclase intergrowths as a result of crystal-magma mixing in the Proterozoic �land rapakivi batholith, SW Finland

Abstract

Finely cellular plagioclase intergrowths have been studied in xenocrystic andesine (An32) and andesine mantled K-feldspars within mafic magmatic enclaves in a quartz-feldspar porphyry from the Proterozoic subvolcanic Hammarudda complex, Aland rapakivi batholith, SW Finland. The cellular intergrowths usually occur as 0.2–2.0 mm mantles around xenocrysts but also as entirely cellular grains, and are built up of a network of two distinct phases: one relatively Na-rich (An31) and one relatively Ca-rich (An50). The grains are also covered by a thin (0.08–0.12 mm), continuous, normally zoned rim outside the cellular mantle. Small inclusions (0.01–0.05 mm) of Fe−Mg minerals are concentrated in the Ca-rich part of the network. Compositionally, the Na-rich phase of the network is close to the inner non-cellular andesine of the xenocrysts. However, it has a lower Or- and a slightly lower An-content. The Ca-rich phase has the same composition as the inner part of the normally zoned rim, which outwards grades into lower An-contents that overlap the An-content of the matrix plagioclases. The cellular network was developed after the andesine xenocrysts (or andesine mantled K-feldspars) were engulfed in mafic magmatic enclaves during a mixing event. The xenocrysts became heated to a temperature just below the liquidus of the mafic magma. Dissolution of the xenocrysts developed a spongy cellular texture which was penetrated by enclave magma. Ca-rich plagioclase crystallized in the cells in equilibrium with the enclave magma, trapping Fe−Mg-rich melt. As the enclaves cooled the outermost thin rim and matrix plagioclases crystallized from the mafic melt. These processes operated in fairly large enclaves, as the one studied here, which has a diameter of 70cm. Smaller enclaves, on the other hand, were cooled more rapidly to temperatures close to the solidus of the enclave magma, and consequently had no time to dissolve the xenoxrysts.