Ce3+-Doped Li2Ca5Gd(BO3)5 Phosphors with Multiple Luminescent Centers and High Pressure Sensitivity under Near UV Excitation.

Abstract

The performance of Ce3+-based phosphors under mechanical high pressures becomes attractive due to the potential application as a visual pressure sensor. Li2Ca5Gd(BO3)5 was selected as the host for the Ce3+ doping. Rietveld refinements reveal that rare earth cations occupy M1, M2, and M3 sites, and indeed, the photoluminescent spectra of Li2Ca5Gd1-xCex(BO3)5 (0.005 ≤ x ≤ 0.15) exhibit the characteristic of multiple activators, defined as CeI, CeII, and CeIII, with the maximal emission wavelength at ∼444, 419, and 378 nm, respectively. The optimal internal and external quantum efficiencies are 86.29% for x = 0.005 and 20.26% for x = 0.10, respectively, under the NUV excitation at 363 nm. In-situ high pressure emission spectra under 375 nm excitation exhibit an overall red-shift, and the linear pressure susceptibilities up to 6.7 GPa for CeI and CeII centers are -390 and -279 cm-1/GPa, respectively, which is probably the largest among Ce3+-doped oxides and oxysalts. Due to the above superiorities, Ce3+-doped LCGB possesses a high potential as a visual pressure sensor, and this is a successful study on the structure-property relationship of inorganic materials.