Ce-Doped Iron Oxide Anticorrosive Coatings: Effect of c(Ce4+):c(Fe3+) Ratio on Structure, Morphology, and Coating Anticorrosion Performance

Abstract

Utilizing hydrothermal methods, Ce-doped iron oxide nanoparticles were synthesized from precursor solutions under different c(Ce4:c(Fe3+) precursor solutions. The effects of the c(Ce4+):c(Fe3+) ratio in the precursor solutions on the nanoparticle morphology and nanoparticle structure of the Ce-doped iron oxide were investigated using X-Ray diffraction, transmission electron microscopy, and scanning electron microscopy. Fourier transform infrared spectroscopy (FTIR) was used to examine the bond energy strength of the Ce-doped iron oxide nanoparticles. The electrochemical properties of the Ce-doped iron oxide nanoparticles were tested using an electrochemical workstation and a saltwater immersion resistance test. The corrosion resistance of Ce-doped iron oxide coatings at different c(Ce4+):c(Fe3+) ratios was systematically analyzed, uncovering corrosion resistance mechanisms and self-healing capabilities. The results show that as the c(Ce4+):c(Fe3+) ratio decreases, the lattice constants of the samples increase along with the average grain size. Both smaller and larger c(Ce4+):c(Fe3+) ratios are detrimental to lattice distortion in α-Fe2O3. The reduced number of valence electrons provided by cerium ions in Ce-doped iron oxide hinders the generation of holes and exerts a minor influence on the crystal band structure, leading to weaker electrochemical stability. The Ce-doped iron oxide coating prepared at a c(Ce4+):c(Fe3+) ratio of 1:60 readily generates a higher number of reactive hydroxyl radicals during corrosion, thus exhibiting enhanced self-healing capabilities and corrosion resistance.