Cavity ring-down spectroscopy of CO2 overtone bands near 830 nm

Abstract

Three bands 4003i–00001 (i=2, 3, 4) of the Fermi pentad of 12C16O2 near 830nm have been recorded with a continuous-wave cavity ring down spectrometer. A sensitivity at the 5×10–11cm−1 level allowed us to obtain line positions and intensities of these very weak bands. The measured line intensities of these three bands together with those published for the 10051–00001 and 10052–00001 bands were used to obtain the effective dipole moment parameters of 12C16O2 for the ΔP=17 series of transitions, where P=2V1+V2+3V3 is a polyad number (Vi (i=1, 2, 3) are vibrational quantum numbers). Comparisons of the measured line positions and intensities of the 4003i–00001 (i=2, 3, 4) bands to those from the AMES and GEISA line lists are given.