Abstract
Photopolymerizations of ((9-carabzolyl)methyl)thiirane (CMT) and ((10-phenothiazinyl)methyl)thiirane (PMT) initiated with di-( tert-butylphenyl)iodonium tetrafluoroborate (BPIT), diphenyliodonium tetrafluoroborate (DPIT), cyclopropyldiphenylsulfonium tetrafluoroborate (CPS) and (η 5-2,4-cyclopentadien-1-yl) [1,2,3,4,5,6-η)-(1-methylethyl)benzene]-iron (+)-hexafluorophosphate(-1) (Irgacure 261) are reported. The influence of temperature and photoinitiator concentration on the rate of polymerization and conversion limit is discussed. The values of initiator exponent and activation energy for the photopolymerizations of CMT and PMT initiated with BPIT in 1,2-dichloroethane solution have been established.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry and Photobiology A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
