Cationic oxides and dioxides of modified sugarcane bagasse beads with applications as low-cost sorbents for direct red 28 dye

Abstract

The direct red 28 (DR28) dye contamination in wastewater blocks the transmission of light into the water body resulting in the inability to photosynthesize by aquatic life. In addition, it is difficult to break down and persist in the environment, and it is also harmful to aquatic life and water quality because of its aromatic structure. Thus, wastewater contaminated with dyes is required to treat before releasing into the water body. Sugarcane bagasse beads (SBB), sugarcane bagasse modified with titanium dioxide beads (SBBT), sugarcane bagasse modified with magnesium oxide beads (SBBM), sugarcane bagasse modified with aluminum oxide beads (SBBA), and sugarcane bagasse modified with zinc oxide beads (SBBZ) for DR28 dye removal in aqueous solution, and they were characterized with several techniques of BET, FESEM-FIB, EDX, FT-IR, and the point of zero charges (pHpzc). Their DR28 dye removal efficiencies were examined through batch tests, adsorption isotherms, and kinetics. SBBM had the highest specific surface area and pore volume, whereas its pore size was the smallest among other materials. The surfaces of SBB, SBBM, SBBT, and SBBA were scaly sheet surfaces with an irregular shape, whereas SBBZ was a coarse surface. Oxygen, carbon, calcium, chloride, sodium, O–H, C–H, C=O, C=C, and C–O–C were found in all materials. The pHpzc of SBB, SBBT, SBBM, SBBA, and SBBZ were 6.57, 7.31, 10.11, 7.25, and 7.77. All materials could adsorb DR28 dye at 50 mg/L by more than 81%, and SBBM had the highest DR28 dye removal efficiency of 94.27%. Langmuir model was an appropriate model for SBB, whereas Freundlich model was a suitable model for other materials. A pseudo-second-order kinetic model well described their adsorption mechanisms. Their adsorptions of the DR28 dye were endothermic and spontaneous. Therefore, they were potential materials for adsorbing DR28 dye, especially SBBM.