Abstract
The oxidation of the titanium(III) ketimido complex, CP* 2TiNCPh 2 (Cp* = C 5Me 5), with AgBPh 4 in the presence of traces of moisture gives the cationic ketimine complex [CP* 2Ti(OH)(HNCPh 2)]BPh 4·Et 2O ( 1). The structure of the complex has been determined by X-ray diffraction. The cation has a pseudo-tetrahedral structure. The TiOH distance is short [1.853(7) Å], indicating TiO double bond character, while the diphenylketimine ligand acts as an N-donor, with a bent TiNC arrangement [145.1(5)°].
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