Abstract
Abstract Two dinuclear nickel complexes (Et4N)[Ni(mbpa)-Ni(dtcEt)] (1) (dtcEt = diethyldithiocarbamate) and [Ni(dadtEt)Ni(dtcMe)](BPh4) (2) (dtcMe = dimethyldithiocarbamate) have been synthesized as models for the active site of acetyl-CoA synthase (ACS). Cyclic voltammograms show that each complex exhibits a reduction wave, in which the reduction potential of the anion 1 exhibits a significant negative shift from that of the cation 2.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
