Abstract

1. Protonation of N,N'-di-p-tolyl-(3,5-di-tert-butyl-4-oxylphenyl)amidinium radical leads to the formation of a cation radical similar in structure to amidinum salts with an s-cis and s-trans-arrangement of the p-tolyl groups relative to the phenoxyl group. 2. Cation radicals formed by protonation of N,N'-di-p-tolyl-N-acetyl-(3,5-di-tertbutyl-4-oxyphenyl) amidinium and N,N-di-phenyl-N'-p-tolyl-(3,5-di-tert-butyl-4-oxylphenyl)amidinium radicals have a symmetric structure with inclusion of the carbonyl C atom and the phenyl ipso C atom in a four-membered 1,3-diazetidinium ring.

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