Cation exchange and leakage as dominant processes in controlling salinity and strontium in sandy and argillaceous coastal aquifer: Insights from hydrochemistry and multi-isotopes

Abstract

Coastal groundwater is crucial for supporting ecosystems and meeting the water needs of coastal communities. However, over-exploitation of groundwater resources, including fresh water and deep brine, leads to groundwater depletion and exacerbates saline intrusion, posing significant challenges to sustainable development. This study focuses on the south bank of Laizhou Bay, a typical area threatened by saline intrusion due to the salt industry’s extraction of deep brine and over-exploitation of fresh groundwater. To assess the impact on salinization processes, we employed hydrochemistry and multi-isotope techniques to study strontium (Sr) distribution and salinization in coastal groundwater, unraveling their origins and explaining hydrochemical processes. The hydrochemical analysis revealed that evaporite dissolution primarily contributes to salinity, especially in deep brine and saline water (TDS > 30 g/L). The relationship between 87Sr/86Sr and chlor-alkali index (CAI) and saturation index (SI) indicated distinct sources of Sr. In fresh and brackish water (<10 g/L), Sr originates from mineral weathering and dissolution (SIs of albite and calcite increase with salinity), while in deep brine and saline water, Sr is influenced by cation exchange (with CAI-Ⅰ and CAI-Ⅱ greater than 0). Additionally, the interplay of anthropogenic input (nitrate), Sr, and EC highlights the differential anthropogenic impact on shallow groundwater, emphasizing the relatively closed environment of deep brine. Multi-isotope analysis showed that the average 87Sr/86Sr of shallow groundwater samples in the cone depression is 0.7112, between that of upstream surface water and shallow groundwater (0.7119) and deep brine and saline water (0.7101), indicating groundwater extraction induces deep brine leakage into shallow groundwater, elevating salinity and Sr concentrations. This poses a direct threat to local water security, including irrigation suitability and health risks of drinking water.In conclusion, we categorized the relationships between 87Sr/86Sr and Sr under different hydrochemical processes into different end-members based on their origins. This offers valuable insights in comparable regions for identifying groundwater salinization and saline intrusion, and the use of Sr and its isotopes can also help trace cation exchange and deep brine leakage in coastal aquifers.