Abstract

Magnetization data are not sufficient for a comprehensive understanding of cation distribution of substituted Li ferrites. Neutron and X-rays diffraction, and Mossbauer experiments were carried out on several Li-Zn and Li-Ti ferrites with general compositions : Fe 2.5-z/2-3t/2-m Li 0.5+t/2-z/2 Zn z Ti t Mn m O 4 (0 < z < 0.7, 0 < t < 0.8, m is either 0 or 0.035). The agreement between Mossbauer, magnetic, X-ray and neutron data give a difinitive answer about the distribution of Zn and Ti substituted lithium ferrites.

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