Abstract

The uranyl ion in malic acid solution has been investigated by polarography and conductometry. Evidence has been presented for the existence of three kinds of chelate species, , , and . Their structures and electrode reactions at various pH values have been established. In the temperature range from 9.1° to 21.5°C the chelates exist as a dimer. On raising the temperature to 28.5°C the depolymerization takes place completely to form a monomer.

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