Abstract
In the title one-dimensional coordination polymer, {[ZnCl2(C18H14N4)]·0.25H2O}n, the ZnII atom is coordinated by two chloride ions and two 4,4′-bis(1H-imidazol-1-yl)biphenyl ligands, generating a distorted tetrahedral ZnCl2N2 geometry. The dihedral angle between the benzene rings of the ligand is 51.0 (1)° and the dihedral angles between the benzene rings and their attached imidazole rings are 18.7 (2) and 45.9 (1)°. The bridging ligand leads to [10-1] polymeric chains in the crystal and the disordered water molecule (occupancy 0.25) forms O—H⋯Cl hydrogen bonds.
Highlights
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry & Materials Science, Northwest University, Xi’an
In the title one-dimensional coordination polymer, {[ZnCl2(C18H14N4)]0.25H2O}n, the ZnII atom is coordinated by two chloride ions and two 4,40 -bis(1H-imidazol-1-yl)biphenyl ligands, generating a distorted tetrahedral ZnCl2N2 geometry
The bridging ligand leads to [101] polymeric chains in the crystal and the disordered water molecule
Summary
ISSN 1600-5368 catena-Poly[[(dichloridozinc)-l-4,40 - 0 bis(1H-imidazol-1-yl)biphenyl-j2N3:N3 ]. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry (Ministry of Education), College of Chemistry & Materials Science, Northwest University, Xi’an
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