Abstract
The CoII ion in the title complex, [Co(SO4)(C13H8N4)(H2O)2]n, has a slightly distorted octahedral coordination environment formed by two O atoms from two symmetry-related bridging sulfate ligands, two N atoms from a bis-chelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water molecules. The bridging sulfate ligands connect CoII ions to form a one-dimensional chain along the b-axis direction. In the crystal structure, intermolecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds link the chains into a three-dimensional network.
Highlights
The CoII ion in the title complex, [Co(SO4)(C13H8N4)(H2O)2]n, has a slightly distorted octahedral coordination environment formed by two O atoms from two symmetryrelated bridging sulfate ligands, two N atoms from a bischelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water molecules
The bridging sulfate ligands connect CoII ions to form a onedimensional chain along the b-axis direction
Symmetry codes: (i) −x+1, y+1/2, −z+1/2; (iii) x, y+1, z; (iv) −x, −y+2, −z; (v) x−1, y, z
Summary
R factor = 0.063; wR factor = 0.100; data-to-parameter ratio = 10.9. The CoII ion in the title complex, [Co(SO4)(C13H8N4)(H2O)2]n, has a slightly distorted octahedral coordination environment formed by two O atoms from two symmetryrelated bridging sulfate ligands, two N atoms from a bischelating 1H-imidazo[4,5-f][1,10]phenanthroline (IPL) ligand and two O atoms from coordinated water molecules. The bridging sulfate ligands connect CoII ions to form a onedimensional chain along the b-axis direction. Intermolecular O—H O, O—H N and N—. H O hydrogen bonds link the chains into a three-dimensional network
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