Abstract
In the crystal structure of the title compound, [Cd(NCSe)2(C7H7NO)2]n, the Cd2+ cation is coordinated by two 3-acetylpyridine ligands and four μ-1,3-bridging selenocyanate anions within a slightly distorted CdN4Se2 octahedron. The asymmetric units consists of one Cd2+ cation, which is situated on a center of inversion, as well as one selenocyanate anion and one 3-acetylpyridine ligand in general positions. The metal cations are μ-1,3-bridged via the selenocyanate anions into chains along the a axis.
Highlights
In the crystal structure of the title compound, [Cd(NCSe)2(C7H7NO)2]n, the Cd2+ cation is coordinated by two 3acetylpyridine ligands and four -1,3-bridging selenocyanate anions within a slightly distorted CdN4Se2 octahedron
The asymmetric units consists of one Cd2+ cation, which is situated on a center of inversion, as well as one selenocyanate anion and one 3-acetylpyridine ligand in general positions
The metal cations are -1,3-bridged via the selenocyanate anions into chains along the a axis
Summary
Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-EythStrasse 2, 24118 Kiel, Germany. R factor = 0.031; wR factor = 0.061; data-to-parameter ratio = 21.0. In the crystal structure of the title compound, [Cd(NCSe)2(C7H7NO)2]n, the Cd2+ cation is coordinated by two 3acetylpyridine ligands and four -1,3-bridging selenocyanate anions within a slightly distorted CdN4Se2 octahedron. The asymmetric units consists of one Cd2+ cation, which is situated on a center of inversion, as well as one selenocyanate anion and one 3-acetylpyridine ligand in general positions. The metal cations are -1,3-bridged via the selenocyanate anions into chains along the a axis
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