Abstract
In the polymeric title compound, [Pb(C6H4NO2)2C6H6N4S2)]n, the PbII ion is located on a twofold axis and coordinated by one N,N′-bidentate diaminobithiazole (DABT) ligand and four O-monodentate isonicotinate anions in a very distorted cis-PbN2O4 octahedral geometry. The carboxylate group of the isonicotinate anion bridges two PbII ions, forming a polymeric chain. The complete DABT molecule is generated by twofold symmetry; its two thiazole rings are twisted with a dihedral angle of 9.5 (2)°. There are no π–π stacking interactions in the title compound, but N—H⋯O and N—H⋯N hydrogen bonds help to stabilize the structure.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Acta Crystallographica Section E Structure Reports Online
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
