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Abstract
In the structure of the title coordination polymer, [Sn(C6H5)3(C6H6O2P)]n or [PhP(H)O2SnIV(Ph)3]n, the SnIV atom is five-coordinate, with the SnC3O2 framework in a trans trigonal–bipyramidal arrangement having the PhP(H)O2 − anions in apical positions. In the crystal, neighbouring polymer chains are linked via C—H⋯π interactions, forming a two-dimensional network lying parallel to (001).
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