Abstract
In the title polymeric complex, [Sn(C6H5)3(C14H16NO3)]n, adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom. The geometry at the five-coordinate Sn atom is trans-C3SnO2 trigonal-bipyramidal.
Highlights
Structure Reports OnlineKey indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.002 A; R factor = 0.019; wR factor = 0.049; data-to-parameter ratio = 18.2
In the title polymeric complex, [Sn(C6H5)3(C14H16NO3)]n, adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis
The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom
Summary
Key indicators: single-crystal X-ray study; T = 100 K; mean (C–C) = 0.002 A; R factor = 0.019; wR factor = 0.049; data-to-parameter ratio = 18.2. In the title polymeric complex, [Sn(C6H5)3(C14H16NO3)]n, adjacent triphenyltin cations are bridged by the N-cyclohexylphthalamate anion through the carboxylate and carbonyl O atoms, forming a helical chain running along the b axis. The amide N atom is a hydrogen-bond donor to the uncoordinated carboxylate O atom. The geometry at the five-coordinate Sn atom is trans-C3SnO2 trigonal-bipyramidal
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