Abstract
The title compound, [Sn(C6H5)3(C17H25O3S)]n, comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The SnIV atom is in a distorted trans-C3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents.
Highlights
The title compound, [Sn(C6H5)3(C17H25O3S)]n, comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain
The SnIV atom is in a distorted transC3SnO2 trigonal-bipyramidal geometry
R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger
Summary
The title compound, [Sn(C6H5)3(C17H25O3S)]n, comprises two symmetry-independent five-coordinated triphenyltin molecules which are linked by carboxylate bridges into a polymeric chain. The SnIV atom is in a distorted transC3SnO2 trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding interactions involving the hydroxyl substituents. Data collection: APEX2 (Bruker, 2008); cell refinement: SAINT (Bruker, 2008); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: XSEED (Barbour, 2001); software used to prepare material for publication: SHELXTL (Sheldrick, 2008)
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