Abstract
In the title coordination polymer, [Cd(4-CPOA)(H2O)3]n (where 4-CPOA2− is the 4-carboxylatophenoxyacetate dianion, C9H6O5), the CdII ion is seven-coordinate, involving four O atoms of two different 4-CPOA2− ligands and three water molecules, arranged in a pentagonal–bipyramidal geometry. Adjacent CdII ions are linked by the 4-CPOA2− groups in bidentate mode, giving rise to a zigzag chain with a closest Cd⋯Cd distance of 10.310 (5) A. The chains are further linked by O—H⋯O hydrogen bonds to form a supramolecular three-dimensional network.
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