Abstract
In the title coordination polymer, [MnCl2(C7H5NS)2]n, the MnII ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites. The MnII ions are connected by two bridging Cl atoms, forming chains parallel to the c axis. The crystal packing can be descibed as alternating layers parallel to (001) featuring π–π stacking interactions with a centroid–centroid distance of 3.6029 (15) Å.
Highlights
MnII ion is located on the intersection of a twofold rotation axis and a mirror plane and adopts an octahedral coordination geometry defined by two mutually trans N atoms from benzothiazole ligands which occupy the axial positions, and four Cl atoms which form the equatorial sites
The MnII ions are connected by two bridging Cl atoms, forming chains parallel to the c axis
The crystal packing can be descibed as alternating layers parallel to (001) featuring – stacking interactions with a centroid–centroid distance of
Summary
Data collection catena-Poly[[trans-bis(1,3-benzothiazolejN)manganese(II)]-di-l-chlorido] Unité de Recherche de Chimie de l’Environnement et Moléculaire Structurale, CHEMS, Université Constantine 1, 25000, Algeria, and bDépartement Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université R factor = 0.042; wR factor = 0.092; data-to-parameter ratio = 14.3.
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